Effects of curing condition of solution cast Nafion® membranes on PEMFC performance

نویسندگان

  • Singaram Vengatesan
  • Eunae Cho
  • Hyoung-Juhn Kim
  • Tae-Hoon Lim
چکیده

−To study the feasibility of applying solution-cast membranes to polymer electrolyte membrane fuel cells (PEMFCs), single cells prepared with solution-cast membranes were tested. The solution cast membranes were fabricated from a commercial Nafion solution under various conditions. Effects of annealing temperature on characteristics of the solution-cast membranes were investigated by measuring water uptake and ionic conductivity of the membranes. Performance of the single cells using the prepared solution cast membranes was evaluated in terms of i-V curves, Nyquist plots, and H2 crossover current density. Based on the results, solution-cast membranes were fabricated by being cured at 150 C for different hours to examine effects of curing time on cell performance. Finally, durability of solutioncast membranes was investigated with operating the single cells for 1,000 hr.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Methanol crossover and selectivity of nafion/heteropolyacid/montmorillonite nanocomposite proton exchange membranes for DMFC applications

In this work, we prepared the nafion/montmorillonite/heteropolyacid nanocomposite membranes for direct methanol fuel cells (DMFCs). The analyses such as X-ray diffraction (XRD), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM) were conducted to characterize the filler dispersion and membrane structure in prepared nanocomposite membranes. XRD patterns of nafion-CsPW-MMT ...

متن کامل

Nafion/Analcime and Nafion/Faujasite Composite Membranes for High Temperature Operation of PEMFC

─The Nafion/zeolite composite membranes were synthesized for polymer electrolyte fuel cells (PEMFCs) by adding zeolite in the matrix of Nafion polymer. Two kinds of zeolites, Analcime and Faujasite, were used. The physicochemical properties of the composite membranes such as water uptake, ion-exchange capacity, hydrogen permeability, and proton conductivity were determined. The fabricated compo...

متن کامل

Modified CNTs/Nafion composite: The role of sulfonate groups on the performance of prepared proton exchange methanol fuel cell’s membrane

A novel Nafion®-based nanocomposite membrane was synthesized to be applied as direct methanol fuel cells (DMFCs). Carbon nanotubes (CNTs) were coated with a layer of silica and then reacted by chlorosulfonic acid to produce sulfonate-functionalized silicon dioxide coated carbon nanotubes (CNT@SiO2-SO3H). The functionalized CNTs were then introduced to Nafion®, and subsequently, methanol permeab...

متن کامل

An overview of organic/inorganic membranes based on sulfonated poly ether ether ketone for application in proton exchange membrane fuel cells

Nowadays, proton exchange membrane fuel cells (PEMFCs) are the most promising green energy conversion devices for portable and stationary applications. Traditionally, these devices were based onperfluoro-sulfonic acid electrolytes membranes, given the commercial name Nafion. Nafion is the mostused electrolyte membrane till now; because of its high electrochemical properties su...

متن کامل

Studies on the SPEEK membrane with low degree of sulfonation as a stable proton exchange membrane for fuel cell applications

Sulfonated poly (ether ether ketone) (SPEEK) with a low degree of sulfonation (DS = 40%) was prepared for proton exchange membrane fuel cells (PEMFC). Poly (ether ether ketone) (PEEK) was sulfonated in concentrated H2SO4 under N2 atmosphere and characterized by the hydrogen nuclear magnetic resonance (H-NMR) technique. After preparation of the SPEEK polymer, the obtained polymer was dissolved i...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2009